Trimethylindium

Trimethylindium
Stereo, skeletal formula of trimethylindium with all implicit hydrogens shown
Stereo, skeletal formula of trimethylindium with all implicit hydrogens shown
Ball and stick model of trimethylindium
Ball and stick model of trimethylindium
Names
Preferred IUPAC name
Trimethylindium
Systematic IUPAC name
Trimethylindigane[1]
Other names
Trimethylindane, indium trimethyl
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.020.183 Edit this at Wikidata
EC Number
  • 222-200-9
UNII
  • InChI=1S/3CH3.In/h3*1H3; checkY
    Key: IBEFSUTVZWZJEL-UHFFFAOYSA-N checkY
  • InChI=1/3CH3.In/h3*1H3;/rC3H9In/c1-4(2)3/h1-3H3
    Key: IBEFSUTVZWZJEL-SGQDGSKVAB
  • C[In](C)C
Properties
InC
3
H
9
Molar mass 159.922 g mol−1
Appearance White, opaque crystals
Density 1.568 g cm−3 (at 20 °C)
Melting point 88 °C (190 °F; 361 K)
Boiling point 134 °C (273 °F; 407 K) (decomposes above 101 °C (214 °F; 374 K))
Reacts
Thermochemistry
150.5-169.7 kJ mol−1
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Pyrophoric
GHS labelling:
GHS02: FlammableGHS05: Corrosive
Danger
H250, H260, H261, H314
P210, P222, P223, P231+P232, P260, P264, P280, P301+P330+P331, P302+P334, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P335+P334, P363, P370+P378, P402+P404, P405, P422, P501
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Trimethylindium, often abbreviated to TMI or TMIn, is the organoindium compound with the formula In(CH3)3. It is a colorless, pyrophoric solid.[2] Unlike trimethylaluminium, but akin to trimethylgallium, TMI is monomeric.[3]

  1. ^ "Trimethylindium - PubChem Public Chemical Database". The PubChem Project. USA: National Center for Biotechnology Information. 27 March 2005. Descriptors Computed from Structure. Retrieved 21 September 2011.
  2. ^ Bradley, D. C.; Chudzynska, H. C.; Harding, I. S. (1997). "Trimethylindium and Trimethylgallium". Inorganic Syntheses. Vol. 31. pp. 67–74. doi:10.1002/9780470132623.ch8. ISBN 978-0-471-15288-0.
  3. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 262. doi:10.1016/C2009-0-30414-6. ISBN 978-0-08-037941-8.

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