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Diethyl ether peroxide

Diethyl ether hydroperoxide
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/C4H10O3/c1-3-6-4(2)7-5/h4-5H,3H2,1-2H3 checkY
    Key: CXWWPQGYBJCHJL-UHFFFAOYSA-N checkY
  • InChI=1/C4H10O3/c1-3-6-4(2)7-5/h4-5H,3H2,1-2H3
    Key: CXWWPQGYBJCHJL-UHFFFAOYAS
  • CCOC(OO)C
  • CC(OCC)OO
Properties
C4H10O3
Molar mass 106.121 g·mol−1
Appearance colorless liquid
Density 1.005 g/cm3
Boiling point 62 to 64 °C (144 to 147 °F; 335 to 337 K) at 18.7 hPa (reduced pressure)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
 Explosive
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 4: Will rapidly or completely vaporize at normal atmospheric pressure and temperature, or is readily dispersed in air and will burn readily. Flash point below 23 °C (73 °F). E.g. propaneInstability 4: Readily capable of detonation or explosive decomposition at normal temperatures and pressures. E.g. nitroglycerinSpecial hazards (white): no code
2
4
4
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Diethyl ether hydroperoxide is the organic compound with the formula C2H5OCH(OOH)CH3. It is a colorless liquid. Diethyl ether hydroperoxide and its condensation products are responsible for the explosive organic peroxides that slowly form upon exposure of diethyl ether to ambient air and temperature conditions.[1][2]

  1. ^ Milas, Nicholas A.; Peeler, Robert L.; Mageli, Orville L. (1954). "Organic Peroxides. XIX. α-Hydroperoxyethers and Related Peroxides". Journal of the American Chemical Society. 76 (9): 2322–2325. Bibcode:1954JAChS..76.2322M. doi:10.1021/ja01638a012.
  2. ^ A. Rieche, R. Meister (1936). "Modellversuche zur Autoxidation der Äther". Angewandte Chemie (in German). 49 (5): 101–103. Bibcode:1936AngCh..49..101R. doi:10.1002/ange.19360490502.
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